Aerosol Mass Spectrometer
Dr. Douglas R Worsnop
Dr. John T. Jayne
Mrs. Cameron Martin
The Aerodyne aerosol mass spectrometer (AMS) is the only currently available instrument capable of providing quantitative size and chemical mass loading information in real-time for non-refractory sub-micron aerosol particles. The AMS couples size-resolved particle sampling and mass spectrometric techniques into a single real-time measurement system. The Aerodyne AMS has been deployed world-wide at fixed sites, and on mobile laboratory, ship and aircraft platforms. Over 100 instruments are in use in industrial, academic and government laboratories.
- Measurement of ambient atmospheric aerosol mass loadings and size distributions for environmental monitoring.
- Emissions characterization of combustion sources. Direct determination of OC emissions indices with simultaneous measurement of plume CO2.
- Eddy correlation flux measurements of aerosol sulfate, nitrate, ammonium, and organic species dry deposition fluxes.
- High time-resolution mapping of fine aerosol properties from affordable mobile (van, small aircraft) platforms.
- Diagnostic for laboratory aerosol sources, flow reactors or aerosol chambers for aerosol physics and chemistry experiments.
- Analysis of chemical composition as a function of particle size for aerosol delivery systems such as metered dose inhalers. High time-resolution allows measurements on a puff-by-puff basis, eliminating need for time-consuming impactor analyses.
- Single particle chemical analysis with light scattering module and time-of-flight mass spectrometer.
- Mass spectrometric detection combined with particle time-of-flight provides information on particle aerodynamic diameter and aerosol composition in a single measurement.
- Quantitative chemical analysis by thermal vaporization and electron impact ionization mass spectrometry. Particle vaporization temperature adjustable from 200 C to 900 C. Laser-induced incandescence vaporization of black carbon under development.
- Real-time, quantitative size resolved aerosol mass measurement for non-refractory fine particulate matter (40 nm to ~1 µm). New inlets to transmit smaller and larger particle size ranges under development.
- Direct sampling of ambient aerosols; no filters or off-line chemical analysis necessary.
- Fast measurement (1 – 10 sec) of particle size distributions and non-refractory chemical composition. Maximum data collection rate of 100 Hz.
Two versions of the Aerodyne AMS are available. The Compact Time-of-Flight AMS (C-ToF-AMS) incorporates a high-performance, compact time-of-flight mass spectrometer and enables continuous monitoring of the mass spectra (1-800 m/z) of all sampled particles at rates as fast as 80 kHz. The detection limit for the C-ToF-AMS is the lowest of the two versions. The High-Resolution ToF AMS (HR-ToF-AMS) also enables continuous acquisition of complete mass spectra of individual particles, and enables the resolution of distinct chemical species based on mass defect. Algorithms are being developed which allow elemental analysis of HR-ToF-AMS data. The properties of the two versions are summarized in the following table.
|Detection Limit* (µg/m3)||Mass Resolving Power (m/Δm)||Mass Range (m/z)|
Coming soon – CC-ToF-AMS
- Size: Approximately 41″W x 24″D x 53″H
- Weight: Approximately 170 kg
- Power: Approximately 600 Watts. Universal power 110VAC/60Hz or 220VAC/50Hz. Vacuum system fully operational on 24 VDC.
- Computer: Current systems are shipped with rack a mounted computer, PIII 3GHz, Intel CoreTM 2 Duo Processor, 512M SDRAM, 160G hard drive, CD-RW, floppy, 10/100 Ethernet port, 8 USB ports, 1 serial port. Flat screen monitor 15” XGA.
- Packaging: Shipped in one reusable container. Total shipping weight ~280 kg.
Light Scattering Module provides additional information for larger particles (>200nm), particularly for large refractory (dust) particles with low non-refractory coatings. Light scattering analysis also can provide information on particle density and distinguish internal/external mixtures.
Negative Ion Detection Option for ToF-AMS (via electron attachment) selectively detects stable anion species, such as sulfate, nitrate and carboxylic acids. Sensitivity is 1000 lower than electron impact (EI). Switchable with standard EI.M
Relative Humidity/Temperature/Pressure probes allow the user to measure ambient relative humidity, temperature and pressure at sampling inlet, with all measurements fully integrated into the data acquisition system.
Beam Width Probe allows measurement of particle shape by measuring the divergence of the particle beam.
Service/Support Contract (3 years) includes spare parts (extra filaments and electron multiplier) and up to two weeks of on-site support. Parts and support are interchangeable, as needed, based on advance payment of fee. Parts will usually be shipped overnight.
Starting in 2014 we made available several important upgrades for the TOF AMS systems.
1) An improved particle sizing module.
2) An improved data acquisition card.
The sizing module, referred to as the efficient particle time of flight (ePTOF) chopper is based on a multiplexed particle beam chopper system with 50% particle throughput (compared to 2%) providing significantly improved signal-to-noise for the particle size measurement.
The new fast data acquisition card operates with 14 bit dynamic range at 1.6 Gs/s digitization rates. The new card will replace the Agilent AP240 in earlier TOF AMS systems. This card supports the new ePTOF particle beam chopper system and has a custom event triggering mode to allow signal particle mass spectra to be recorded.
The Soot Particle Aerosol Mass Spectrometer (SP-AMS) makes real-time, in situ measurements of black carbon containing particles. The SP-AMS instrument combines the technologies from two proven, commercial aerosol instruments: Aerodyne’s Aerosol Mass Spectrometer (AMS) (Canagaratna et al., Mass. Spec. Rev., 26, 185-222, 2007) for quantitive aerosol mass loadings and Droplet Measurement Technologies’ Single Particle Soot Photometer (SP2) (Baumgardner et al., GRL, 31, LO6117, doi:10.10129/2003GL018883, 2004) for black carbon. The SP-AMS uses laser-induced incandescence of absorbing soot particles to vaporize both the coatings and elemental carbon cores within the ionization region of the AMS, providing a unique and selective method for measuring the mass of the refractory carbon cores (i.e., black carbon mass), the mass and chemical composition of any coating material (e.g,. organics, sulfates, nitrates, etc.), and particle size and morphology.
The SP-AMS has been deployed in several field campaigns for measurements of ambient aerosol (Queens, NY, 2009), biomass burning plumes (FLAME III, 2009) and ship plumes (CalNex 2010).
Development of an aerosol mass spectrometer for size and composition analysis of submicron particles, J.T. Jayne, D.C. Leard, X. Zhang, P. Davidovits, K.A. Smith, C.E. Kolb, and D.R. Worsnop, Aerosol Sci. Technol., 33, 49-70, 2000.
Ambient Aerosol Sampling with an Aerosol Mass Spectrometer, J. L. Jimenez, J. T. Jayne, Q. Shi, C.E. Kolb, D.R. Worsnop, I. Yourshaw, J.H. Seinfeld, R.C. Flagan, X. Zhang, K.A. Smith, J. Morris, and P. Davidovits, J. Geophys. Res. – Atmospheres, 108, (D7), 8425, doi:10.1029/2001JD001213, 2003.
A new Time-of-Flight Aerosol Mass Spectrometer (ToF-AMS) – Instrument Description and First Field Deployment, F. Drewnick, S.S. Hings, P.F. DeCarlo, J.T. Jayne, M. Gonin, K. Fuhrer, S. Weimer, J.L. Jimenez, K.L. Demerjian, S. Borrmann, D.R. Worsnop. Aer. Sci. Technol., 39, 637–658, 2005.
A Field-Deployable High-Resolution Time-of-Flight Aerosol Mass Spectrometer, P. F. DeCarlo, J.R. Kimmel, A. Trimborn, M.J. Northway, J.T. Jayne, A.C. Aiken, M. Gonin, K. Fuhrer, T. Horvath, K. Docherty, D.R. Worsnop, and J.L. Jiménez, , Anal. Chem., 78, 8281-8289, 2006.
Chemical and Microphysical Characterization of Ambient Aerosols with the Aerodyne Aerosol Mass Spectrometer, M.R. Canagaratna, J.T. Jayne, J.L. Jiménez, J.D. Allan, M.R. Alfarra, Q. Zhang, T.B. Onasch, F. Drewnick, H. Coe, A. Middlebrook, A. Delia, L.R. Williams, A.M. Trimborn, M.J. Northway, P.F. DeCarlo, C.E. Kolb, P. Davidovits, and D.R. Worsnop, Mass Spectrom. Rev., 26, 185-222, 2007.
♦ A complete list of publications related to the AMS and electronic files are available at: http://cires.colorado.edu/jimenez/ams-papers.html.
♦ For more information on our aerosol mass spectrometers: email@example.com
♦ For instrument support: firstname.lastname@example.org
♦ For recent AMS data acquisition software downloads follow this link: https://sites.google.com/site/tofamsdaq/
♦ For a list of past AMS Users Meeting please follow this link: http://tinyurl.com/AMS-Users
♦ For more information also visit: http://writeondeadline.com/