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A Novel Dual Cell gas analysis system for continuous, accurate, simultaneous measurement of concentrations of Carbon Dioxide isotopologues.
A room temperature QCL laser from Alpes Lasers, is operated in the 2310 to 2315 cm-1 range
to APPLICATIONS:
ADVANTAGES:
0.2δ in one second, or 0.03δ in 300 sec.
Click here for a Typical isotopologue-specific spectral scan in the 2310 cm-1 region, taken from the TDLWintel data acquisition screen, using the dual-cell QCL spectrometer. ADVANTAGES
of Novel Dual Cell Approach (sample
+ reference)
TECHNICAL SPECIFICATIONS: Technical specifications for the CO2 Isotope Analyzer with both LN2-cooled detectors and TE-cooled detectors are given below:
1. The RMS noise definition is defined by the 1 sigma standard deviation of a data stream with a 1 Hz sampling frequency for the ratio of the minor isotope to the major isotope. The values given are for simultaneous detection of all three isoptopologues. 2. The absolute concentrations are based on the periodic addition of calibration gases using automated solenoid valve (included). 3. The sampling frequency of 1 to 20 Hz is the electronic processing speed. The gas exchange time constant (1/e) in the 0.3 liter volume sampling cell is tau=0.05 seconds with a 420 liter-per-minute vacuum pump (optional). REFERENCES: "New Method
for Isotopic Ratio Measurements of Atmospheric Carbon Dioxide Using a 4.3
micron Pulsed Quantum Cascade Laser," Nelson, D. D.; McManus, J. B.;
Herndon, S. C.; Zahniser, M. S.; Tuzson, B.; Emmenegger, L. Submitted
to Applied Physics B. "A high precision pulsed QCL spectrometer for measurements of stable isotopes of carbon dioxide," McManus, J. B.; Nelson, D. D.; Shorter, J. H.; Jiménez, R.; Herndon, S.; Saleska, S.; Zahniser, M. S., J. Modern Optics, 52, 2309-2321 (2005). "What are the instrumentation requirements for measuring the isotopic composition of net ecosystem exchange of CO2 using eddy covariance methods?" Saleska, S. R.; Shorter, J.; Herndon, S.; Jimenéz, R.; McManus, B.; Nelson, D.; Zahniser M., Isotopes in Environmental and Health Studies, 42 (1), 117 (2006).
For more information about this product or
associated R&D service contact:
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Aerodyne Research, Inc. 45 Manning Road Billerica, MA 01821-3976 978 663-9500 |
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